Nanopicture of the Day

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March 27, 2004

Dip Pen Etching

Source:  Chad Mirkin

      References:

"DPN-Generated Nanostructures Made of Gold, Silver, and Palladium" Hua Zhang and Chad A. Mirkin Chem. Mater.; 2004; ASAP Web Release Date: 24-Mar-2004; (Article) DOI: 10.1021/cm0305507
 

Description:

Dip Pen Nanolithography (DPN) uses the tip of an atomic force microscope (AFM) to deposit a tiny layer of a chemical on a surface.  That layer can be used like as a protective mask to etch away the surrounding material, leaving the material under the chemical intact.  This method allows even metals to be patterned at the sub-100 nm scale.  In this image, arrays of figures are patterned in silver after being "drawn" with mercaptohexadecanoic acid (MHA) "ink" and subsequent chemical etching.  These results show how one can use DPN as an alternative to more complex and costly procedures such as electron beam lithography to generate nanostructures from inorganic materials.
 

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