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January 16, 2004
Nanocable Aligned Nanocrystals
Source: Ying-Chun Zhu et.al.
References:
Description:
Integrated nanostructures are of great interest due to a a wide range of possible technological applications in electronics, optics, biomedicine, and mechanics. Two major fundamental steps in nanotechnological processes are (i) control of nanocrystal structures; and (ii) arrangement of nanostructures within the building blocks of special nanodevices. Much progress has been made in these areas, but there is no "one" solution yet.
ZnS, a wide-band-gap semiconductor, is a well-known luminescence material having
prominent applications in displays, sensors, and lasers. One-dimensional
(1D) ZnS nanostructures, such as nanowires, nanobelts, nanocables, and nanotubes,
have recently been synthesized by several groups. The present work developed an
effective method for fabricating novel ZnS nanostructures, that is, ZnS-core/carbon-sheath
nanocables and nanocable-aligned ZnS tetrapod nanocrystals (single crystalline
cubic ZnS with triangular-prism branches stretching out in four {111}
directions.) The nanocable-aligned tetrapods and the core-sheath heterostructure
have modulated composition, interfaces, and crystal orientations, which may thus
induce modulated electronic and optical properties and find applications in
nanoelectronics and photonics.
Above are images of nanocable-aligned ZnS tetrapods. (a) Aligned ZnS tetrapods.
(b) Nanocable passing through the center of the tetrapod. (c) Tetrapod image
viewed along the [111] direction; (d) viewed along the [] direction; (e) viewed
along the [100] direction.
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