Nanopicture of the Day

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February 23, 2004

Templateless Nanowire Arrays

Source:  Jing Zhu

      References:

K. Peng, Y. Yan, S. Gao, J. Zhu "Dendrite-Assisted Growth of Silicon Nanowires in Electroless Metal Deposition" Adv. Funct. Mater. 13, No. 2, 127-132 (2003).

Description:

A simple and inexpensive room-temperature synthesis method has been used to create the large-area silicon nanowire array shown here via electroless metal deposition without the use of templates.  This research highlights the silver dendrite-assisted growth of single-crystalline silicon nanowires, and their possible self-assembling nanoelectrochemistry growth mechanism. The growth of silicon nanowires was carried out through an electroless metal deposition process in a conventional autoclave containing aqueous HF and AgNO3 solution near room temperature. In order to explore the mechanism and prove the centrality of silver dendrites in the growth of silicon nanowires, other etching solution systems with different metal species were also investigated in this work. The morphology of etched silicon substrates strongly depends upon the composition of the etching solution, especially the metal species. These experimental results prove that the simultaneous formation of silver dendrites is a guarantee of the preservation of free-standing nanoscale electrolytic cells on the silicon substrate, and also assists in the final formation of silicon nanowire arrays on the substrate surface.

 

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